Cooperative reaction chemistry derived from a borata-diene framework.
نویسندگان
چکیده
The bifunctional frustrated BH(-)/B hydridoborate nucleophile/borane Lewis acid pair 6 is prepared starting from the borata-diene 3 by a sequence of sequential protonation/hydride attachment, followed by hydroboration with Piers' borane [HB(C6F5)2]. The trans-1,2-bifunctional system 6 reduced carbon monoxide eventually to the aldehyde product 10.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 7 شماره
صفحات -
تاریخ انتشار 2016